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State of matter

States of matter are the distinct forms that different phases of matter take on. Historically, the distinction is made based on qualitative differences in bulk properties. Solid is the state in which matter maintains a fixed volume and shape; liquid is the state in which matter maintains a fixed volume but adapts to the shape of its container; and gas is the state in which matter expands to occupy whatever volume is available.
This diagram shows the nomenclature for the different phase transitions.

More recently, distinctions between states have been based on differences in molecular interrelationships. Solid is the state in which intermolecular attractions keep the molecules in fixed spatial relationships. Liquid is the state in which intermolecular attractions keep molecules in proximity, but do not keep the molecules in fixed relationships. Gas is that state in which the molecules are comparatively separated and intermolecular attractions have relatively little effect on their respective motions. Plasma is a highly ionized gas that occurs at high temperatures. The intermolecular forces created by ionic attractions and repulsions give these compositions distinct properties, for which reason plasma is described as a fourth state of matter.[1][2]

Forms of matter that are not composed of molecules and are organized by different forces can also be considered different states of matter. Fermionic condensate and the quark–gluon plasma are examples.

Although solid, gas and liquid are the most common states of matter on Earth, much of the baryonic matter of universe is in the form of hot Plasma, both as rarefied interstellar medium and as dense stars.

States of matter may also be defined in terms of phase transitions. A phase transition indicates a change in structure and can be recognized by an abrupt change in properties. By this definition, a distinct state of matter is any set of states distinguished from any other set of states by a phase transition. Water can be said to have several distinct solid states.[3] The appearance of superconductivity is associated with a phase transition, so there are superconductive states. Likewise, liquid crystal states and ferromagnetic states are demarcated by phase transitions and have distinctive properties.
Because solids have thermal energy or heat capacity, their atoms vibrate about fixed mean positions within the ordered (or disordered) lattice. Shown here are the one-dimensional normal modes of vibration in a crystalline solid. The amplitude of the motion has been exaggerated, and is actually much smaller than the lattice parameter. The entire spectrum of lattice vibrations in a crystalline or glassy network plays a key role in the kinetic theory of solids.


Classical states

Solid
Main article: Solid

The particles (ions, atoms or molecules) are packed closely together. The forces between particles are strong enough so that the particles cannot move freely but can only vibrate. As a result, a solid has a stable, definite shape, and a definite volume. Solids can only change their shape by force, as when broken or cut.
A crystalline solid: atomic resolution image of strontium titanate. Brighter atoms are Sr and darker ones are Ti.

In crystalline solids, the particles (atoms, molecules, or ions) are arranged in an ordered three-dimensional structure. There are many different crystal structures, and the same substance can have more than one structure (or solid phase). For example, iron has a body-centred cubic structure at temperatures below 912 °C, and a face-centred cubic structure between 912 and 1394 °C. Ice has fifteen known crystal structures, or fifteen solid phases which exist at various temperatures and pressures.[4]

Solids can be transformed into liquids by melting, and liquids can be transformed into solids by freezing. Solids can also change directly into gases through the process of sublimation.

Liquid
Main article: Liquid
Structure of a classical monatomic liquid. Atoms have many nearest neighbors in contact, yet no long-range order is present.

The volume is definite if the temperature and pressure are constant. When a solid is heated above its melting point, it becomes liquid. Intermolecular (or interatomic or interionic) forces are still important, but the molecules have enough energy to move relative to each other and the structure is mobile. This means that the shape of a liquid is not definite but is determined by its container. The volume is usually greater than that of the corresponding solid, the most well known exception being water, H2O. The highest temperature at which a given liquid can exist is its critical temperature.[5]

Gas
Main article: Gas

In a gas, the molecules have enough kinetic energy so that the effect of intermolecular forces is small (or zero for an ideal gas), and the typical distance between neighboring molecules is much greater than the molecular size. A gas has no definite shape or volume, but occupies the entire container in which it is confined. A liquid may be converted to a gas by heating at constant pressure to the boiling point, or else by reducing the pressure at constant temperature.

At temperatures below its critical temperature, a gas is also called a vapor, and can be liquefied by compression alone without cooling. A vapor can exist in equilibrium with a liquid (or solid), in which case the gas pressure equals the vapor pressure of the liquid (or solid).

A supercritical fluid (SCF) is a gas whose temperature and pressure are above the critical temperature and critical pressure respectively. It has the physical properties of a gas, but its high density confers solvent properties in some cases which lead to useful applications. For example, supercritical carbon dioxide is used to extract caffeine in the manufacture of decaffeinated coffee.[6]

Non-classical states

Crystalline vs. glassy
Schematic representation of a random-network glassy form (top) and ordered crystalline lattice (bottom) of identical chemical composition.

In crystalline solids, the atoms or molecules that compose the solid are packed closely together. In mineralogy and crystallography, a crystal structure is a unique arrangement of atoms in a crystal. A specific symmetry or crystal structure is composed of a Bravais lattice which is typically represented by a single unit cell. The unit cell is periodically repeated in three dimensions on a lattice.

Non-crystalline or amorphous or glassy solids are often referred to as supercooled liquids, but possess the mechanical properties of both a solid and a liquid, depending on the time scale under consideration. In their molecular structure, their molecules do not exhibit the long-range order exhibited by crystalline substances. In addition, while a glassy solid does exhibit some viscous flow and plastic deformation, this only occurs on geologic timescales. Thus, it behaves mechanically as a solid for all practical intents and purposes—and most experimental timescales. Common examples are silicate glasses, synthetic rubber and polystyrene and other polymers. Many amorphous solids soften into liquids when heated above their glass transition temperatures, at which the molecules become mobile.

Generally speaking, the atomic or molecular structure of glass exists in a metastable state with respect to its crystalline form. Glass would convert into a more stable crystalline form, but the rate of this conversion is slow. This essentially reflects the basic physics of glass, the glass transition, and its formation from a non-equilibrium supercooled liquid state.[7][8][9] Much work has been done to elucidate the primary microstructural features of glass forming substances (e.g. silicates) on both small (microscopic) and large (macroscopic) scales. One emerging school of thought is that a glass is simply the "limiting case" of a polycrystalline solid at small crystal size. Within this framework, domains, exhibiting various degrees of short-range order, become the building blocks of both metals and alloys, as well as glasses and ceramics. The microstructural defects of both within and between these domains provide the natural sites for atomic diffusion, and the occurrence of viscous flow and plastic deformation in solids.[10]

* Note: Because solids have thermal energy, their atoms vibrate about fixed mean positions within the ordered (or disordered) lattice. The spectrum of lattice vibrations in a crystalline or glassy network provides the foundation for the kinetic theory of solids. This motion occurs at the atomic level, and thus cannot be observed or detected without highly specialized equipment—such as that used in spectroscopy.


Liquid crystal states
Main article: Liquid crystal

Liquid crystal states have properties intermediate between mobile liquids and ordered solids. For example, the nematic phase consists of long rod-like molecules such as para-azoxyanisole, which is nematic in the temperature range 118–136 °C.[11] In this state the molecules flow as in a liquid, but they all point in the same direction (within each domain) and cannot rotate freely.

Other types of liquid crystals are described in the main article on these states. Several types have technological importance, for example, in liquid crystal displays.

Magnetically ordered

Transition metal atoms often have magnetic moments due to the net spin of electrons which remain unpaired and do not form chemical bonds. In some solids the magnetic moments on different atoms are ordered and can form a ferromagnet, an antiferromagnet or a ferrimagnet.

In a ferromagnet—for instance, solid iron—the magnetic moment on each atom is aligned in the same direction (within a magnetic domain). If the domains are also aligned, the solid is a permanent magnet, which is magnetic even in the absence of an external magnetic field. The magnetization disappears when the magnet is heated to the Curie point, which for iron is 768 °C.

An antiferromagnet has two networks of equal and opposite magnetic moments which cancel each other out, so that the net magnetization is zero. For example, in nickel(II) oxide (NiO), half the nickel atoms have moments aligned in one direction and half in the opposite direction.

In a ferrimagnet, the two networks of magnetic moments are opposite but unequal, so that cancellation is incomplete and there is a non-zero net magnetization. An example is magnetite (Fe3O4), which contains Fe2+ and Fe3+ ions with different magnetic moments.

Low-temperature states

Superfluids
Main article: Superfluid

Close to absolute zero, some liquids form a second liquid state described as superfluid because it has zero viscosity or infinite fluidity. This was discovered in 1937 for helium which forms a superfluid below the lambda temperature of 2.17 K. In this state it will attempt to 'climb' out of its container.[12] It also has infinite thermal conductivity so that no temperature gradient can form in a superfluid.

These properties are explained by the theory that the common isotope helium-4 forms a Bose–Einstein condensate (see next section) in the superfluid state. More recently, Fermionic condensate superfluids have been formed at even lower temperatures by the rare isotope helium-3 and by lithium-6.[13]

Bose-Einstein condensates
Main article: Bose-Einstein condensate

In 1924, Albert Einstein and Satyendra Nath Bose predicted the "Bose-Einstein condensate," sometimes referred to as the fifth state of matter.

In the gas phase, the Bose-Einstein condensate remained an unverified theoretical prediction for many years. In 1995 the research groups of Eric Cornell and Carl Wieman, of JILA at the University of Colorado at Boulder, produced the first such condensate experimentally. A Bose-Einstein condensate is "colder" than a solid. It may occur when atoms have very similar (or the same) quantum levels, at temperatures very close to absolute zero (–273.15 °C).

Rydberg molecules

One of the metastable states of strongly non-ideal plasma is Rydberg matter, which forms upon condensation of excited atoms. These atoms can also turn into ions and electrons if they reach a certain temperature. In April 2009, Nature reported the creation of Rydberg molecules from a Rydberg atom and a ground state atom,[14] confirming that such a state of matter could exist.[15] The experiment was performed using ultracold rubidium atoms.

High-energy states

Plasma (ionized gas)
Main article: Plasma (physics)

Plasmas or ionized gases can exist at temperatures starting at several thousand degrees C. Two examples of plasma are the charged air produced by lightning, and a star such as our own sun.

As a gas is heated, electrons begin to leave the atoms, resulting in the presence of free electrons, which are not bound to an atom or molecule, and ions, which are chemical species that contain unequal number of electrons and protons, and therefore possess an electrical charge. The free electric charges make the plasma electrically conductive so that it responds strongly to electromagnetic fields. At very high temperatures, such as those present in stars, it is assumed that essentially all electrons are "free," and that a very high-energy plasma is essentially bare nuclei swimming in a sea of electrons. Plasma is the most common state of non-dark matter in the universe.

A plasma can be considered as a gas of highly ionized particles, but the powerful interionic forces lead to distinctly different properties, so that it is usually considered as a different phase or state of matter.

Quark-gluon plasma
Main article: Quark-gluon plasma

This is a state of matter discovered at the CERN in 2000, in which the quarks that would normally make up protons and neutrons are freed and can be observed individually, similar to splitting molecules into atoms. This state of matter allows scientists to observe the properties of individual quarks, and not just theorize. See also Strangeness production.

Other proposed states
Main article: List of states of matter

Degenerate matter
Main article: Degenerate matter

Under extremely high pressure, ordinary matter undergoes a transition to a series of exotic states of matter collectively known as degenerate matter. These are of great interest to astrophysics, because these high-pressure conditions are believed to exist inside stars that have used up their nuclear fusion "fuel", such as white dwarfs and neutron stars.

Supersolid
Main article: Supersolid

A supersolid is a spatially ordered material (that is, a solid or crystal) with superfluid properties. A supersolid is a solid, but exhibits so many other properties that many argue it is another state of matter.[16]

String-net liquid

When in a normal solid state, the atoms of matter align themselves in a grid pattern, so that the spin of any electron is the opposite of the spin of all electrons touching it. But in a string-net liquid, atoms are arranged in some pattern which would require some electrons to have neighbors with the same spin. This gives rise to some curious properties, as well as supporting some unusual proposals about the fundamental conditions of the universe itself.

Superglass
Main article: Superglass

A superglass is a phase of matter which is characterized at the same time by superfluidity and a frozen amorphous structure.

See also

* Condensed matter physics
* Cooling curve
* Phase (matter)
* Supercooling
* Superheating


Notes and references

1. ^ D.L. Goodstein (1985). States of Matter. Dover Phoenix. ISBN 978-0486495064.
2. ^ A.P. Sutton (1993). Electronic Structure of Materials. Oxford Science Publications. pp. 10–12. ISBN 978-0198517542.
3. ^ M. Chaplin (20 August 2009). "Water phase Diagram". Water Structure and Science. http://www.lsbu.ac.uk/water/phase.html. Retrieved 2010-02-23.
4. ^ M.A. Wahab (2005). Solid State Physics: Structure and Properties of Materials. Alpha Science. pp. 1–3. ISBN 1842652184.
5. ^ F. White (2003). Fluid Mechanics. McGraw-Hill. p. 4. ISBN 0-07-240217-2.
6. ^ G. Turrell (1997). Gas Dynamics: Theory and Applications. John Wiley & Sons. pp. 3–5. ISBN 0471975737. http://books.google.com/?id=-6qF7TKfiNIC&pg=PA3.
7. ^ S.V. Nemilov (1994). Thermodynamic and Kinetic Aspects of the Vitreous State. CRC Press. ISBN 0849337828. http://books.google.com/?id=wmBhYJPMolAC&pg=PP1.
8. ^ J. Zarzycki (1991). Glasses and the Vitreous State. Cambridge University Press. ISBN 0521355826. http://books.google.com/?id=bZFOAAAAIAAJ&printsec=frontcover.
9. ^ R. Zallen (1998). The Physics of Amorphous Solids. Wiley. pp. 3–5. ISBN 0471299413. http://books.google.com/?id=V0jr74rPdUIC&printsec=frontcover.
10. ^ J.C. Phillips (1982). "The Physics of Glass". Physics Today 35: 27. doi:10.1063/1.2914932.
11. ^ Shao, Y.; Zerda, T. W. (1998). "Phase Transitions of Liquid Crystal PAA in Confined Geometries". Journal of Physical Chemistry B 102 (18): 3387–3394. doi:10.1021/jp9734437.
12. ^ J.R. Minkel (20 February 2009). "Strange but True: Superfluid Helium Can Climb Walls". Scientific American. http://www.scientificamerican.com/article.cfm?id=superfluid-can-climb-walls. Retrieved 2010-02-23.
13. ^ L. Valigra (22 June 2005). "MIT physicists create new form of matter". MIT News. http://web.mit.edu/newsoffice/2005/matter.html. Retrieved 2010-02-23.
14. ^ V. Bendkowsky et al. (2009). "Observation of Ultralong-Range Rydberg Molecules". Nature 458 (7241): 1005. doi:10.1038/nature07945. PMID 19396141.
15. ^ V. Gill (23 April 2009). "World First for Strange Molecule". BBC News. http://news.bbc.co.uk/2/hi/science/nature/8013343.stm. Retrieved 2010-02-23.
16. ^ G. Murthy et al. (1997). "Superfluids and Supersolids on Frustrated Two-Dimensional Lattices". Physical Review B 55: 3104. doi:10.1103/PhysRevB.55.3104.


External links

* 2005-06-22, MIT News: MIT physicists create new form of matter Citat: "... They have become the first to create a new type of matter, a gas of atoms that shows high-temperature superfluidity."
* 2003-10-10, Science Daily: Metallic Phase For Bosons Implies New State Of Matter
* 2004-01-15, ScienceDaily: Probable Discovery Of A New, Supersolid, Phase Of Matter Citat: "...We apparently have observed, for the first time, a solid material with the characteristics of a superfluid...but because all its particles are in the identical quantum state, it remains a solid even though its component particles are continually flowing..."
* 2004-01-29, ScienceDaily: NIST/University Of Colorado Scientists Create New Form Of Matter: A Fermionic Condensate
* Short videos demonstrating of States of Matter, solids, liquids and gases by Prof. J M Murrell, University of Sussex

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